Resistivity Imaging Identifies Potential Contaminant Transport Pathway

Resistivity Imaging maps potential subsurface transport pathway in south-central Oklahoma

Lithochimeia was retained to investigate complaints of strong hydrocarbon odors from a spring on in south-central Oklahoma.  

Initial sampling indicated the presence of hydrocarbons in waters flowing from the spring after larger rainfall events.   Pipelines transporting hydrocarbons traversed the property up-gradient from the spring that exhibited hydrocarbon odors.  Lithochimeia conducted a Resistivity Survey to examine the region between the pipelines and the spring for evidence of a pathway existed between the pipelines and the spring.  The Resistivity Survey involved obtaining data from forty north-south transects between the pipelines and the spring.

Electrical current was injected into the subsurface via the electrodes of the array and the resulting electrical activity at the surface was measured and interpreted to produce images representing the electrical properties of the subsurface.

The image resulting form the survey revealed potential subsurface transport pathways between the pipelines and the spring.  The karst geology of the area and diagonally oriented faults were visible as highly resistive cavernous porosity as well as clay and silt filled porosity in the subsurface. 

This 2-D rendering was mapped in 3-D to better visualize the subsurface geometry of the potential transport pathway.

Monitoring wells were installed to both confirm the results of the resistivity survey and to provide access to groundwater for sampling.

Groundwater sampling revealed hydrocarbon signatures similar to those found at the spring.

Widespread Salt Contamination Mapped on 15,000 Acre Ranch

Lithochimeia was retained to investigate current and historic saltwater releases on a large ranch in northeast OK . 

Review of air photos showed numerous areas potentially impacted by salt contamination on the ranch.

Lithochimeia conducted frequency domain electromagnetic (EM) Terrain Conductivity Surveys using a Geonics EM-31-MK2 ground conductivity meter over areas potentially contaminated by saltwater in areas surrounding tank batteries, pumping units, flowline routes, and areas of visible surface damage.  EM Surveys use the principle of electromagnetic induction to measure the conductivity of the subsurface based on soil electrical properties and chemistry of pore fluids.  EM Surveys do not require ground contact and therefore allow rapid data acquisition.   Data can be processed and viewed in near real time.

In all, over 2 million square meters (540 acres) of surface area was surveyed using the EM-31-MK2 ground conductivity meter.  This was accomplished in in less than four weeks because of the ability to rapidly acquire data this geophysical method provides.

Results of the Terrain Conductivity Survey indicated probable widespread contamination of large portions of the ranch by high salinity produced water. The results of the Terrain Conductivity Survey were then confirmed by soil and water sampling and laboratory analysis.

Characterization of contamination this widespread through air-photo analysis, on-ground visual inspection and direct sampling alone would require collecting hundreds of samples and would be very expensive. When applicable, modern geophysical methods provide cost-effective and time-efficient solutions for projects requiring both large amounts of information while maintaining high data density.

Geophysical Investigation Uncovers Hidden Contamination

Lithochimeia was retained to investigate high salinity liquids that had pooled on the surface of a private landowner’s property in Hughes County, Oklahoma.  Lithochimeia was tasked to characterize the extent of contamination and identify the potential source.

Client interviews revealed that a large diameter plastic pipe had been recently installed to transport frac water and flowback water. Over a portion of the property, this line was located adjacent to a steel line carrying natural gas.

A Terrain Conductivity Survey was planned and executed using Geonics EM-31-MK2 over the impacted area as well as the surrounding surface.  Electromagnetic (EM) Surveys use the principle of electromagnetic induction to measure the conductivity of the subsurface based on soil properties and chemistry of pore fluids.  EM Surveys do not require ground contact and therefore allow rapid data acquisition.   Data can be processed and viewed in near real time.

The data obtained was processed in the field, and the resulting contoured map of terrain conductivity showed that the EM Survey clearly imaged the location of the steel gas line and the area of elevated conductivity associated with the pooled saltwater.

the resulting contoured map of terrain conductivity also showed an detached and unexplained area of high conductivity to the west of the original focus of the survey.  As the result , the the survey area expanded to determine the extent and nature of the d unexplained area of high conductivity observed in the original survey.

The expanded EM-31 Survey produced a contoured terrain conductivity map that displayed a large plume of conductive material in the subsurface apparently emanating from the vicinity of the pipeline northwest of the original survey focus.  The data suggested a breach of the plastic line that had been undetected until the EM-31 Survey was conducted and processed. 

Relying exclusively on soil sampling and visual observation would not have been able to detect this subsurface plume of conductive fluids.  The high data density and efficiency of the EM-31 Terrain Conductivity Survey allowed for a larger area to be rapidly characterized.  Early detection of salt contamination will reduce injury to soil and ground water and reduce remedial costs for the responsible party.

Lithochimeia Presents Poultry Waste Papers at the 2009 International Symposium on Environmental Science and Technology in Shanghai, China

News 01

Bert Fisher and Larry Hight presented research papers concerning poultry waste disposal and pollution in the Illinois River Watershed at the 2009 International Symposium on Environmental Science and Technology held at the Songjiang Campus of Donghua University in  Shanghai, China,  June 2-5, 2009 (http://www.isest.com.cn/).  
Fisher, J. B., R. L. Olsen, F. M. Soster, B. Engle and M. Smith. 2009. The history of poultry waste contamination in the Illinois River Watershed as determined from sediment cores collected from Tenkiller Ferry Reservoir (Oklahoma, United States) In: Progress in Environmental Science and Technology, Volume II, Part B. Proceedings of the 2009 International Symposium on Environmental Science and Technology, Shanghai, China, June 2-5, 2009, Shengcai Li, Yajun Wang, Fengxia Cao, Ping Huang and Yao Zhang, eds., Science Press, Beijing, P. R. China, pp 1222-1237. (ISEST01.pdf)

news 02

Fisher, J. B., R. L. Hight, R. van Waasbergen, B. Engle and M. Smith. 2009. Estimates of the mass generated, disposal timing and the spatial distribution of disposal sites within the Illinois River Watershed (Oklahoma and Arkansas, United States). In: Progress in Environmental Science and Technology, Volume II, Part B. Proceedings of the 2009 International Symposium on Environmental Science and Technology, Shanghai, China, June 2-5, 2009, Shengcai Li, Yajun Wang, Fengxia Cao, Ping Huang and Yao Zhang, eds. , Science Press, Beijing, P. R. China, pp 1238-1247. (ISEST02.pdf)Lithochimea Presents Research Compilation at 2009 International Petroleum & Biofuels Environmental Conference in Houston, TX.

Bert Fisher presented a paper entitled, Using Multiple Soil Salinity Assessment Methods in the Development of Geochemical and Geophysical Salt Contamination Maps for Use in Litigation, at the 16th Annual International Petroleum & Biofuels Environmental Conference held in Houston, TX, November 3-5, 2009 (For a full agenda for all papers presented at the 16th Annual International Petroleum & Biofuels Environmental Conference see http://ipec.utulsa.edu/Conf2009/Agenda%2010-3-09/Agenda09.htm).

Fisher, J. B. 2009. Using Multiple Soil Salinity Assessment Methods in the Development of Geochemical and Geophysical Salt Contamination Maps for Use in Litigation, International Petroleum & Biofuels Environmental Conference, Houston, TX, November 3-5, 2009, Abstract. (IPEC2009.pdf)

Lithochimea Presents Case Studies at 2010 International Petroleum & Biofuels Environmental Conference in San Antonio, TX.

Bert Fisher and Kerry Sublette presented a series of case studies illustrating the use of various techniques to characterize the vadose zone migration of oilfield brine contamination at the 17th Annual International Petroleum & Biofuels Environmental Conference.  The paper demonstrated the use of visual observations, geophysical measurements and the chemistry of soil samples in determining the source and extent of oilfield brine contamination at real-world sites in Oklahoma and Kansas.

Fisher, J. B. and K. L. Sublette. 2010. Case Studies of Surface and Vadose Zone Migration of Oilfield Brine Contamination. 2010 17th Annual International Petroleum & Biofuels Environmental Conference San Antonio, TX – August 30 – September 2, 2010  

PRESENTATION)

(Full Agenda: for the 17th Annual International Petroleum & Biofuels Environmental Conference see http://ipec.utulsa.edu/Conf2010/2010agenda.html)

Lithochimeia Presents Study of Poultry Waste Marker Constituents in Edge of Field Runoff within the Illinois River Watershed at the 2010 Governor’s Water Conference and Oklahoma Water Research Symposium in Norman, OK.

Bert Fisher presented a research paper concerning the inorganic chemical markers in poultry waste and how the presence and relative abundance of those markers link the chemistry of water running off poultry waste applied fields to poultry waste and poultry waste contaminated soil 

Smolen, M., J. B. Fisher and R. Olsen. 2010. Poultry waste marker constituents in edge of field runoff samples from the Illinois River Waterhsed.  Oklahoma Governor’s Water Conference and Water Research Symposium, Norman, OK  (October 26-27, 2010) 

(ABSTRACT / PRESENTATION)

( For all 2010 Oklahoma Water Research Symposium Abstracts see:  http://environ.okstate.edu/OKWATER/abstracts_all.asp).